Follow the guide below to unlock new characters.

Adult Gohan - Super Saiyan) – Clear Mission 32 with S rank or higher
Bardock – Clear Mission 44 with A rank or higher
Cell Jr – Clear Mission 58 with A rank or higher
Cell Perfect Form – Clear Mission 26 with S rank or higher
Cooler Final Form – Clear Mission 47 with S rank or higher
Dabura – Clear Mission 32 with S rank or higher
Evil Buu – Clear Mission 34 with S rank or higher
Frieza Soldier – Clear Mission 11 with A rank or higher
Ginyu – Clear Mission 43 with S rank or higher
God of Destruction Beerus – Clear Mission 59 with S rank or higher
Kid Buu – Clear Mission 35 with S rank or higher
Legendary Super Saiyan Broly – Clear Mission 49 with S rank or higher
Majin Vegeta – Clear Mission 33 with S rank or higher
Recoome – Clear Mission 12 with S rank or higher
Super Saiyan Broly – Clear Mission 49 with A rank or higher
Super Saiyan Gotenks – Clear Mission 37 with A rank or higher
Super Saiyan 2 Goku – Clear Mission 36 with A rank or higher
Super Saiyan 2 Teen Gohan – Clear Mission 26 with S rank or higher
Super Saiyan 3 Goku – Clear Mission 39 with S rank or higher
Super Saiyan 3 Gotenks – Clear Mission 37 with S rank or higher
Whis – Clear Mission 59 with S rank or higher